Boomerang: Redundancy Improves Latency and Throughput in Payment-Channel Networks

In multi-path routing schemes for payment-channel networks, Alice transfers funds to Bob by splitting them into partial payments and routing them along multiple paths. Undisclosed channel balances and mismatched transaction fees cause delays and failures on some payment paths. For atomic transfer schemes, these straggling paths stall the whole transfer. We show that the latency of transfers reduces when redundant payment paths are added. This frees up liquidity in payment channels and hence increases the throughput of the network. We devise Boomerang, a generic technique to be used on top of multi-path routing schemes to construct redundant payment paths free of counterparty risk. In our experiments, applying Boomerang to a baseline routing scheme leads to 40% latency reduction and 2x throughput increase. We build on ideas from publicly verifiable secret sharing, such that Alice learns a secret of Bob iff Bob overdraws funds from the redundant paths. Funds are forwarded using Boomerang contracts, which allow Alice to revert the transfer iff she has learned Bob's secret. We implement the Boomerang contract in Bitcoin Script

Structure and Reactivity of the Distonic and Aromatic Radical Cations of Tryptophan

In this work, we regiospecifically generate and compare the gas-phase properties of two isomeric forms of tryptophan radical cations-a distonic indolyl N-radical (H3N+ - TrpN(center dot)) and a canonical aromatic pi (Trp(center dot+)) radical cation. The distonic radical cation was generated by nitrosylating the indole nitrogen of tryptophan in solution followed by collision-induced dissociation (CID) of the resulting protonated N-nitroso tryptophan. The p-radical cation was produced via CID of the ternary [Cu-II(terpy)(Trp)](center dot 2+) complex. CID spectra of the two isomeric species were found to be very different, suggesting no interconversion between the isomers. In gas-phase ion-molecule reactions, the distonic radical cation was unreactive towards n-propylsulfide, whereas the pi radical cation reacted by hydrogen atom abstraction. DFT calculations revealed that the distonic indolyl radical cation is about 82 kJ/mol higher in energy than the pi radical cation of tryptophan. The low reactivity of the distonic nitrogen radical cation was explained by spin delocalization of the radical over the aromatic ring and the remote, localized charge (at the amino nitrogen). The lack of interconversion between the isomers under both trapping and CID conditions was explained by the high rearrangement barrier of ca. 137 kJ/mol. Finally, the two isomers were characterized by infrared multiple-photon dissociation (IRMPD) spectroscopy in the similar to 1000-1800 cm(-1) region. It was found that some of the main experimental IR features overlap between the two species, making their distinction by IRMPD spectroscopy in this region problematic. In addition, DFT theoretical calculations showed that the IR spectra are strongly conformation-dependent